Persistence of a Ru <sub>3</sub> ( <i>μ</i> ‐CO) <sub>3</sub> (CO) <sub>5</sub> Cluster Bound to a PNNP “Expanded Pincer” Ligand in Different Protonation States

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چکیده

Ru3(μ-CO)3(CO)5-type clusters bound to the dinucleating PNNP expanded pincer ligand are described. Deprotonation of a methylene linker gives an anionic triruthenium cluster featuring dearomatized ligand. Interestingly, H2 activation by resulting appears not proceed through metal-ligand cooperativity.

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ژورنال

عنوان ژورنال: European Journal of Inorganic Chemistry

سال: 2022

ISSN: ['1434-1948', '1099-0682']

DOI: https://doi.org/10.1002/ejic.202200191